The list, compiled by US magazine Fortune, ranks the top 500 US companies by revenue. Soaring energy prices are thought to be responsible for Exxon's rise.
Exxon's revenue was US$339.94 billion compared with Wal-Mart's US$315.65 billion. Profits were US$36.13 billion and US$11.23 billion respectively.
General Motors takes third place in 2006's list.
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